87420-17-5

Upstream product

• 100-39-0 benzyl bromide 
• 76529-59-4 Propionic acid (1R,2S,3R,4S)-3-[benzenesulfonyl-(3,5-dimethyl-phenyl)-amino]-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester 
• 87420-26-6 (1R,2S,3R)-3-[N-Phenylsulfonyl-N-(3,5-dimethylphenyl)amino]bornan-2-ol 

Downstream Products

• 108781-61-9 2-Hydroxy-2-methyl-3-phenyl-propionic acid (1R,2S,3R,4S)-3-[benzenesulfonyl-(3,5-dimethyl-phenyl)-amino]-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester 

Relevant academic research and scientific papers

STRUCTURE AND DIASTEREOSELECTIVITY OF THE α-HYDROXYLATION OF CHIRAL ESTER ENOLATES BY MOLYBDENUM PEROXO COMPLEX

Scope and limitations of the diastereoselective α-hydroxylation of chiral ester enolates by MoO5.Py.HMPT were investigated.An improved synthesis of natural (-)-verrucarinolactone ((-)-(2S,3R)-2-hydroxy-3-methyl-pentanolide) is described.

INFLUENCE OF CATION COMPLEXING SOLVENT ADDITIVES AND FUNCTIONAL GROUPS IN ASYMMETRIC ALKYLATIONS OF ESTERS VIA LITHIUM ENOLATES

Highly diastereoselective alkylations of propionates of chiral alcohols derived from (+)-camphor are described.It is demonstrated that steric shielding as well as cation complexation are important for stereoselection.The latter effects are in part rationa