874209-67-3Relevant academic research and scientific papers
Synthesis of sterically controlled chiral β-amino alcohols and their application to the catalytic asymmetric sulfoxidation of sulfides
Jeong, Yong-Chul,Huang, Yao Dong,Choi, Soojin,Ahn, Kwang-Hyun
, p. 3497 - 3501 (2007/10/03)
Sterically hindered and enantiomerically pure β-amino alcohols 8a and 8b were prepared from the enantiomerically pure aziridine-2-carboxylic acid menthol ester 13. Vanadium complexes of the chiral Schiff-base ligands prepared from the β-amino alcohols catalyze an efficient enantioselective sulfoxidation of alkyl aryl sulfides, while enantioselectivities as high as 96% ee can be observed in the sulfoxidation of benzyl aryl sulfides.
