87428-68-0Relevant academic research and scientific papers
1-LITHIO-1-BENZENESULFINYL-2-TRIMETHYLSILYLETHANE AS A 2-TRIMETHYLSILYLVINYL ANION EQUIVALENT IN REACTIONS WITH ALHEDYDES, KETONES AND EPOXIDES
Hsiao, C-N.,Shechter, H.
, p. 2371 - 2374 (2007/10/02)
Aldehydes, ketones and epoxides give adducts with 1-lithio-1-benzenesulfinyl-2-trimethylsilylethane which upon neutralization eliminate benezenesulfenic acid efficiently at 76 deg C to yield trans-3-(trimethylsilyl)allyl alcohols and trans-4-(trimethylsilyl)-3-alken-1-ols.
A NEW SYNTHESIS OF UNSATURATED ALDEHYDES
Cutting, Ian,Parsons, Philip J.
, p. 2021 - 2022 (2007/10/02)
Treatment of 3-trimethylsilylallylic alcohols with phenylsulphenyl chloride gives unstable allylic sulphoxides which rearrange and are then hydrolysed to unsaturated aldehydes.
