874291-97-1

Basic information

• Product Name: Phosphinic acid, 2-propenyl-, phenylmethyl ester
• CAS NO: 874291-97-1
• Molecular Formula: C10H13O2P
• Molecular Weight: 196.186
• Mol File: 874291-97-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Phosphinic acid, 2-propenyl-, phenylmethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphinic acid, 2-propenyl-, phenylmethyl ester(874291-97-1)
• EPA Substance Registry System: Phosphinic acid, 2-propenyl-, phenylmethyl ester(874291-97-1)

Safety Data

• Hazardous Substances Data: 874291-97-1(Hazardous Substances Data)

Upstream product

• 18108-16-2 benzyl hypophosphite 
• 106-95-6 allyl bromide 
• 66899-05-6 allyl-H-phosphinic acid 
• 100-51-6 benzyl alcohol 

Downstream Products

• 874292-18-9 O-benzyl 2-propen-1-yl-[[(N-benzyloxy-L-γ-glutamyl(α-benzyl ester)-L-leucyl)amino]methyl]phosphinate 
• 874292-11-2 O-benzyl 2-propen-1-yl(aminomethyl)phosphinate 
• 874292-04-3 O-benzyl 2-propen-1-yl[(N-tritylamino)methyl]phosphinate 

Relevant articles and documents

Direct monoalkylation of alkyl phosphinates to access H-phosphinic acid esters

Simple alkyl phosphinates prepared by the silicate esterification method can be alkylated under Barbier-like conditions with butyl lithium at -78 °C followed by warming to room temperature. The method is limited to the more reactive electrophile such as allylic bromides and alkyl iodides. With these electrophiles good yields of H-phosphinic acid esters are generally obtained in a straightforward manner. Georg Thieme Verlag Stuttgart.