874292-41-8

Upstream product

• 189210-87-5 (1S,2S,4S,5S)-(+)-2,5-dimethylcyclohexane-1,4-diol bis(methanesulfonate) 
• 106-42-3 para-xylene 
• 131063-54-2 (1S,2S,4S,5S)-(+)-1,4-dihydroxy-2,5-dimethylcyclohexane 

Downstream Products

• 874292-42-9 2,5-dimethyl-7-azabicyclo[2.2.1]heptane 

Relevant academic research and scientific papers

C2-Symmetric nitroxides and their potential as enantioselective oxidants

The synthesis and evaluation of four C2-symmetric nitroxides are presented. The nitroxides were evaluated for their ability to mediate the oxidation of several alcohols and found to have good catalytic activity. One enantioenriched nitroxide was found to kinetically resolve selected secondary alcohols with very modest selectivities.

Syntheses of novel chiral 2,5-dialkyl-7-azabicyclo[2.2.1]heptanes and 2,5-dialkyl-7-thiobicyclo[2.2.1]heptanes

New C2-symmetric chiral amines with a rigid bicyclic framework have been synthesized via hydrogenation of monoazides catalyzed by 5% Pd/C in methanol. Enantiomerically pure 2,5-dialkyl-7-thiobicyclo[2.2.1]heptanes were made from readily available materials.