874305-93-8

Basic information

• Product Name: C₂₇H₃₆⁽²⁾H₂N₆O₉
• Synonyms: C₂₇H₃₆⁽²⁾H₂N₆O₉
• CAS NO: 874305-93-8
• Molecular Weight: 592.618
• Mol File: 874305-93-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₇H₃₆⁽²⁾H₂N₆O₉(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₇H₃₆⁽²⁾H₂N₆O₉(874305-93-8)
• EPA Substance Registry System: C₂₇H₃₆⁽²⁾H₂N₆O₉(874305-93-8)

Safety Data

• Hazardous Substances Data: 874305-93-8(Hazardous Substances Data)

Upstream product

• 100-51-6 benzyl alcohol 
• 407629-42-9 t-BuOCO-L-Pro-Gly-Gly-Gly-OCH₂Ph₂ 
• 24424-99-5 di-tert-butyl dicarbonate 
• 15761-39-4 1-(tert-butoxycarbonyl)-L-proline 
• 874305-85-8 Boc-GPGGG-OCH₂Ph 
• 42492-65-9 N-(tert-butoxycarbonyl)glycine-2,2-d₂ 

Relevant articles and documents

Cation dependence of chloride ion complexation by open-chained receptor molecules in chloroform solution

Seventeen peptides, most having the sequence GGGPGGG, but differing in the C- and N-terminal ends, have been studied as anion-complexing agents. These relatively simple, open-chained peptide systems interact with both chloride and the associated cation. Changes in the N- and C-terminal side chains appear to make little difference in the efficacy of binding. NMR studies suggest that the primary interactions involve amide NH contacts with the chloride anion, and CD spectral analyses suggest a concomitant conformational change upon binding. Changes in binding constants, which are expected in different solvents, also suggest selective solvent interactions with the unbound host that helps to preorganize the open-chained peptide system. Significant differences are apparent in complexation strengths when the heptapeptide chain is shortened or lengthened or when the relative position of proline within the heptapeptide is varied.