87436-98-4Relevant academic research and scientific papers
Gold(I)-catalyzed addition of diphenyl phosphate to alkynes: Isomerization of kinetic enol phosphates to the thermodynamically favored isomers
Lee, Phil Ho,Kim, Sundae,Park, Aeri,Chary, Bathoju Chandra,Kim, Sunggak
supporting information; experimental part, p. 6806 - 6809 (2010/12/19)
(Chemical Equation Presented) Gold, gold, or... gold? It depends on the (gold) catalyst whether the product of thermodynamic or kinetic control is formed in an unprecedented hydrophosphoryloxylation approach to enol phosphates (see scheme). A third catalyst, [(C6F5) 3PAuOTf], was found to be exceedingly effective for the previously unknown isomerization of kinetic enol phosphates to the thermodynamically favored isomers. Tf=trifluoromethanesulfonyl; R=alkyl, cyclohexyl, Ph.
NEW SYNTHESES OF ALLYLSILANES AND VINYLSILANES BY MEANS OF PhMe2Si-AlEt2
Okuda, Yasuhiro,Sato, Mitsuyoshi,Oshima, Koichiro,Nozaki, Hitosi
, p. 2015 - 2018 (2007/10/02)
The reaction of allylic phosphates with the title organoaluminium reagent (PhMe2Si-AlEt2) provides allylsilanes in good yields.Cross coupling of enol phosphates with PhMe2Si-Mtl (Mtl = AlEt2 or MgMe) produces vi
