874466-03-2Relevant academic research and scientific papers
Proton-abstraction mechanism in the palladium-catalyzed intramolecular arylation: Substituent effects
Garcia-Cuadrado, Domingo,De Mendoza, Paula,Braga, Ataualpa A. C.,Maseras, Feliu,Echavarren, Antonio M.
, p. 6880 - 6886 (2008/02/05)
The regioselectivity observed in the intramolecular palladium-catalyzed arylation of substituted bromobenzyldiarylmethanes as well as theoretical results demonstrate that the Pd-catalyzed arylation proceeds by a mechanism involving a proton abstraction by
Proton abstraction mechanism for the palladium-catalyzed intramolecular arylation
Garcia-Cuadrado, Domingo,Braga, Ataualpa A. C.,Maseras, Feliu,Echavarren, Antonio M.
, p. 1066 - 1067 (2007/10/03)
Under the usual conditions, the Pd-catalyzed arylation does not involve an electrophilic aromatic substitution reaction. On the basis of DFT calculations, we propose a mechanism for the Pd-catalyzed arylation that involves a proton abstraction by a carbon
