Cas 87456-41-5,α-(camphorsulfonyloxy)acetophenone

87456-41-5

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Basic information

Product Name: α-(camphorsulfonyloxy)acetophenone
Synonyms: α-(camphorsulfonyloxy)acetophenone
CAS NO:87456-41-5
Molecular Formula:
Molecular Weight: 350.436
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: α-(camphorsulfonyloxy)acetophenone(CAS DataBase Reference)
NIST Chemistry Reference: α-(camphorsulfonyloxy)acetophenone(87456-41-5)
EPA Substance Registry System: α-(camphorsulfonyloxy)acetophenone(87456-41-5)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 87456-41-5(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 87456-41-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,7,4,5 and 6 respectively; the second part has 2 digits, 4 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 87456-41:
(7*8)+(6*7)+(5*4)+(4*5)+(3*6)+(2*4)+(1*1)=165
165 % 10 = 5
So 87456-41-5 is a valid CAS Registry Number.

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87456-41-5Relevant academic research and scientific papers

Preparation of benzene and Its Reactivity toward Carbonyl Compounds

Hatzigrigoriou, Evangelia,Varvoglis, Anastasios,Bakola-Christianopoulou, Maria

, p. 315 - 318 (2007/10/02)

The title compound is prepared and used for the direct α-((10-camphorsulfonyl)oxylation) of various ketones and carbonyl compounds with an active methylene group.Its reaction with 2-butanone and 4-methyl-2-pentanone yields predominantly the corresponding 1-sulfonyloxy derivatives.The stereoselectivity of the reaction is studied by using benzoylacetone, ethyl benzoylacetate, and propiophenone.In some reactions 10-camphorsulfonyl peroxide is formed as a byproduct.

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