87470-76-6

Upstream product

• 100-44-7 benzyl chloride 
• 1032959-15-1 1-thiophenyl-4-O-(4',6'-O-benzylidiene-β-D-glucopyranosyl)-β-D-glucopyranoside 
• 100-52-7 benzaldehyde 
• 27894-87-7 phenyl β-D-glucopyranosyl-(1->4)-1-thio-β-D-glucopyranoside 
• 97974-20-4 (2R,3R,4S,5R,6S)-4,5-Bis-benzyloxy-2-benzyloxymethyl-6-phenylsulfanyl-tetrahydro-pyran-3-ol 

Downstream Products

• 87470-77-7 phenyl 2,3,6,2',3',4'-hexa-O-benzyl-1-thio-β-cellobioside 
• 213012-40-9 phenyl 2,3,6-tri-O-benzyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-benzyl-1-thio-β-D-glucopranoside 
• 87470-78-8 phenyl 2,3,6,2',3',4'-hexa-O-benzyl-6'-O-methyl-1-thio-β-cellobioside 
• 213012-44-3 tert-Butyl-dimethyl-[(2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-((2R,3R,4S,5R,6S)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-phenylsulfanyl-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-2-ylmethoxy]-silane 
• 213012-45-4 [(2R,3R,4R,5R,6S)-4,5-Bis-benzyloxy-2-benzyloxymethyl-6-((2R,3R,4S,5R,6S)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-phenylsulfanyl-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-3-yloxy]-tert-butyl-dimethyl-silane 
• 213012-46-5 tert-Butyl-dimethyl-[(2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-((2R,3S,4R)-4-benzyloxy-2-benzyloxymethyl-3,4-dihydro-2H-pyran-3-yloxy)-tetrahydro-pyran-2-ylmethoxy]-silane 
• 213012-47-6 [(2R,3R,4R,5R,6S)-4,5-Bis-benzyloxy-6-((2R,3S,4R)-4-benzyloxy-2-benzyloxymethyl-3,4-dihydro-2H-pyran-3-yloxy)-2-benzyloxymethyl-tetrahydro-pyran-3-yloxy]-tert-butyl-dimethyl-silane 

Relevant academic research and scientific papers

Iron(iii) chloride modulated selective 1,2-trans glycosylation based on glycosyl trichloroacetimidate donors and its application in orthogonal glycosylation

The development of a new glycosylation method for efficient stereoselective synthesis of β-gluco- and galactosides from their corresponding armed trichloroacetimidate donors mediated by 10 mole% of FeCl3 has been focused. FeCl3 has a

HYDROGENOLYSIS OF THE BENZYLIDENE ACETALS OF THIOGLYCOSIDES WITH THE LiAlH4-AlCl3 REAGENT. SYNTHESIS OF PARTIALLY BENZYLATED THIOGLYCOSIDE DERIVATIVES

Reductive hydrogenolysis of phenyl 2,3-di-O-benzyl-4,6-O-benzylidene-1-thio-β-D-gluco- (4) and -galactopyranoside (8) and phenyl 2,3,6,2',3'-penta-O-benzyl-4',6'-O-benzylidene-1-thio-β-cellobioside (15) with the LiAlH4-AlCl3 reagent resulted in the corres