874814-27-4

Upstream product

• 1432028-75-5 3-(dimethylamino)-2-methyl-1-(p-tolyl)prop-2-en-1-one 
• 17356-08-0 thiourea 

Downstream Products

• 1432028-74-4 1,2-bis(5-methyl-4-(p-tolyl)pyrimidin-2-yl)disulfide 
• 1432028-72-2 1,2-bis(5-methyl-4-(p-tolyl)pyrimidin-2-yl)sulfide 
• 1432028-70-0 [(1,2-bis(5-methyl-4-(p-tolyl)pyrimidin-2-yl)sulfide){Cu(μ-I)}₂]₂*MeCN 
• 1432028-64-2 Cu₆(5-methyl-4-(p-tolyl)pyrimidine-2-thiolato)₆ 

Relevant academic research and scientific papers

An unusual 30-membered copper(i) cluster derived from the C-S bond cleavage and its use in heterogeneous catalysis

The Cu(i)-mediated C-S bond cleavage of 5-methyl-4-(p-tolyl)pyrimidine-2- thiol (mtpmtH) gave one 30-nuclear cluster [Cu30I16(mtpmt) 12(μ10-S4)], one polymeric complex [(bmtpms)Cu-(μ-I)]n and one tetranuclear complex [(bmptmds){Cu(μ-I)}2]2; the 30-nuclear cluster displayed excellent catalytic performances in the coupling reactions of N-heterocycles and arylboronic acids and could be recycled and reused.