1432028-64-2Relevant academic research and scientific papers
An unusual 30-membered copper(i) cluster derived from the C-S bond cleavage and its use in heterogeneous catalysis
Li, Hong-Xi,Zhao, Wei,Li, Hai-Yan,Xu, Zhong-Lin,Wang, Wen-Xia,Lang, Jian-Ping
supporting information, p. 4259 - 4261 (2013/07/05)
The Cu(i)-mediated C-S bond cleavage of 5-methyl-4-(p-tolyl)pyrimidine-2- thiol (mtpmtH) gave one 30-nuclear cluster [Cu30I16(mtpmt) 12(μ10-S4)], one polymeric complex [(bmtpms)Cu-(μ-I)]n and one tetranuclear complex [(bmptmds){Cu(μ-I)}2]2; the 30-nuclear cluster displayed excellent catalytic performances in the coupling reactions of N-heterocycles and arylboronic acids and could be recycled and reused.
