874918-25-9Relevant academic research and scientific papers
A new selective approach to 1,1-bis(silyl)-2-arylethenes and 1,1-bis(silyl)-1,3-butadienes via sequential silylative coupling-heck coupling reactions
Pawluc, Piotr,Hreczycho, Grzegorz,Marciniec, Bogdan
, p. 8676 - 8679 (2006)
A novel selective route to 1,1-bis(silyl)-1-alkenes has been developed. Sequential one-pot silylative coupling exo-cyclization of 1,2- bis(dimethylvinylsiloxy)ethane followed by the reaction with Grignard reagents leads to the desired 1,1-bis(silyl)ethene
An improved synthesis of 2-aryl-1,1-bis(trimethylsilyl)ethenes
Pawluc, Piotr,Hreczycho, Grzegorz,Madalska, Martyna,Szudkowska, Justyna,Kubicki, Maciej,Marciniec, Bogdan
experimental part, p. 3843 - 3847 (2010/03/03)
A series of new 2-aryl-1,1-bis(trimethylsilyl)ethenes containing ortho-, meta-, and para-substituted aryl or heteroaryl groups has been efficiently synthesized using an improved two-step approach based on a silylative coupling cyclization-Heck coupling/Gr
Intramolecularly donor-stabilized silenes: Part 6. the synthesis of 1-[2,6-bis(dimethylaminomethyl)phenyl]silenes and their reaction with aromatic aldehydes
B?umer, Ute,Reinke, Helmut,Oehme, Hartmut
, p. 229 - 239 (2007/10/03)
The intramolecularly donor-stabilized silenes ArR1SiC(SiMe 3)2 (3a-d) (3a: R1 = Me; 3b: R1 = t-Bu; 3c: R1 = Ph; 3d: R1 = SiMe3; Ar = 2,6-(Me2NCH2
