875018-26-1Relevant articles and documents
Asymmetric synthesis of propargylamides via 3,3′-disubstituted binaphthol-modified alkynylboronates
Wu, T. Robert,Chong, J. Michael
, p. 15 - 18 (2007/10/03)
(Chemical Equation Presented) Alkynylboronates derived from 3,3′-disubstituted-2,2′-binaphthols react with various N-acylimines to give the expected chiral propargylamides with up to 99% ee. This new methodology was applied to the first enantioselective s