87514-08-7Relevant academic research and scientific papers
Reactions of 2-phenylthio-2-cycloalkenones and 2-[phenyl(thiomethyl)]-2-cycloalkenones. Synthesis of some useful chiral and achiral intermediates
Vankar,Kumaravel,Bhattacharya,Vankar,Kaur
, p. 4829 - 4840 (2007/10/02)
The allyl acetates derived from 2-phenylthio-2-cyclopentenone, 2-phenylthio-2-cyclohexenone, 2-[phenylthio(methyl)]-2-cyclopentenone and 2-[phenylthio(methyl)]-2-cyclohexenone have been hydrolysed by pig liver acetone powder to obtain the corresponding al
Enantiocomplementary resolution of 2-phenylthio-2-cyclopentenol and 2-phenylthio-2-cyclohexenol using the same lipase
Takano,Yamada,Iida,Ogasawara
, p. 592 - 596 (2007/10/02)
Both racemic 2-phenylthio-2-cyclopentenol (±)-(3a) and 2-phenylthio-2-cyclohexenol (±)-(3b) afford the corresponding (R)-acetates (R)-4a,b and the unreacted (S)-alcohols (S)-3a,b, respectively, in excellent optical and chemical yields on treatment with vi
CLEAVAGE OF SILICON-VINYL CARBON BOND BY nBu4NF
Oda, Hiroji,Sato, Mitsuyoshi,Morizawa, Yoshitomi,Oshima, Koichiro,Nozaki, Hitosi
, p. 2877 - 2880 (2007/10/02)
Dimethylphenylsilyl- and diphenylmethylsilyl-vinyl carbon bonds are cleaved with nBu4NF.Desilylation of 1-phenylthio-1-trimethylsilyl-1-alkenes in the presence of aldehyde moiety gives carbanion adducts.
