87515-26-2Relevant academic research and scientific papers
Anomeric O-alkylation, 15: New 2/1-type surfactants by anomeric O-alkylation of mannofuranose
Terjung, Andreas,Jung, Karl-Heinz,Schmidt, Richard R.
, p. 1313 - 1321 (2007/10/03)
New 2/1-type surfactants were synthesized from glycerol derivatives 2a-e having a long-chain 2-O-alkyl substituent. Transformation of 2a-d into 1,3-di-O-trifluoromethanesulfonates 4a-d and their use in anomeric O-alkylation of mannofuranose 7 afforded aft
1,3(R):4,6(R)-DI-O-BENZYLIDEN-D-MANNIT ALS AUSGANGSPRODUKT FUER DIE SYNTHESE OPTISCH AKTIVER GLYCERIN-DERIVATE
Schubert, Thomas,Kunisch, Franz,Welzel, Peter
, p. 2211 - 2217 (2007/10/02)
Starting from the di-O-benzylidene-D-mannitol derivative 11, certain types of optically active glycerol derivatives can be prepared with a minimum of protecting group chemistry.This is exemplified by an efficient synthesis of 2-O-alkyl glyceric acid derivatives 22 and 23.
