87544-20-5

Upstream product

• 107-05-1 3-chloroprop-1-ene 
• 71-43-2 benzene 
• 201230-82-2 carbon monoxide 
• 24850-33-7 allyltributylstanane 
• 109586-43-8 o-(2-propenyl)phenyl trifluoromethanesulfonate 
• 83500-76-9 o-(Isopropylthio)-phenyl methyl sulphide 
• 1730-25-2 allylmagnesium bromide 
• 88284-48-4 2-(trimethylsilyl)phenyl trifluoromethanesulfonate 
• 583-53-9 2,3-dibromobenzene 
• 593-60-2 Vinyl bromide 
• 91-13-4 α,α'-dibromo-o-xylene 

Downstream Products

• 1301264-04-9 2-hexylidene-2,3,3a,4,9,9a-hexahydro-1Hcyclopenta[b]naphthalene 
• 1301264-05-0 2-hexyl-3a,4,9,9a-tetrahydro-1Hcyclopenta[b]naphthalene 
• 110413-17-7 2-[2-(oxiran-2-ylmethyl)benzyl]oxirane 

Relevant academic research and scientific papers

Palladium-catalyzed reaction of arynes with a bis-π-allyl palladium complex. An efficient method for the synthesis of 1,2-diallylated derivatives of benzene

Palladium-catalyzed reaction of arynes with a bis-π-allyl palladium complex, an amphiphilic catalytic allylating agent, afforded 1,2-diallylated derivatives of benzene in good yields. (C) 2000 Elsevier Science Ltd.

Benzocyclodecane derivatives with antitumor activity

A compound which is a benzocyclodecane of the formula I: wherein: at positions 8-9 and 11-12 independently represents a single or double bond, —R1 is ═O, or —OR7, R7 is H, C1-C7 alkanoyl, benzoyl, Cs

Pd-Catalyzed Cross-Coupling of Haloarenes and Chloroarene-Cr(CO) 3 Complexes with Stabilized Vinyl- and Allylaluminium Reagents

The palladium-catalyzed cross-coupling of intramolecularly stabilized divinyl- and diallylaluminium compounds 1 and 2 with haloarenes and chloroarene-Cr(CO)3 complexes has been studied. The coupling products were obtained in high yields (up to

SELECTIVE MONO-ARYLATION AND -ALKYLATION OF BIS(ALKYLTHIO)BENZENES; THE IMPORTANCE OF STERIC EFFECTS IN THE NICKEL-CATALYZED CROSS-COUPLING OF ARYL ALKYL SULPHIDES WITH GRIGNARD REAGENTS

Synthetically useful procedures to effect selective conversion of C-S into C-C bonds have been developed by taking advantage of the sensitivity of reactions of Grignard reagents with aryl alkyl sulphides, catalyzed by low-valent nickel species, to steric effects.It is shown that the course of these reactions is influenced by the steric requirements of both the aryl and the alkyl moieties of the sulphides.Thus, selective mono-arylation and alkylation of easily available bis(alkylthio)benzenes can be effected in medium to high yields.This allows the introduction of two different aryl or alkyl groups into the benzene nucleus by sequential substitution of the two alkylthio functions.