87549-81-3

Basic information

• Product Name: Stannane, [2-[(triphenylstannyl)methyl]-1,3-propanediyl]bis[triphenyl-
• CAS NO: 87549-81-3
• Molecular Formula: C58H52Sn3
• Molecular Weight: 1105.18
• Mol File: 87549-81-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Stannane, [2-[(triphenylstannyl)methyl]-1,3-propanediyl]bis[triphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Stannane, [2-[(triphenylstannyl)methyl]-1,3-propanediyl]bis[triphenyl-(87549-81-3)
• EPA Substance Registry System: Stannane, [2-[(triphenylstannyl)methyl]-1,3-propanediyl]bis[triphenyl-(87549-81-3)

Safety Data

• Hazardous Substances Data: 87549-81-3(Hazardous Substances Data)

Upstream product

• 4167-90-2 triphenylstannyllithium 
• 87597-81-7 2-[(triphenylstannyl)methyl]-1,3-propanediol dimethanesulfonate 

Downstream Products

• 519-73-3 triphenylmethane 
• 10271-32-6 1,1-dimethyl-3,3-diphenyl-2,3-dihydro-1H-indene 
• 87922-35-8 1,3,5-triphenyl-2,4,6-trithia-1,3,5-tristannaadamante 

Relevant articles and documents

Transfer off hydrogen from carbon-hydrogen bonds. Synthesis, structure, and reactions of tris[(triphenylstannyl)methyl]methane

Compounds in which a carbon-hydrogen bond is adjacent to several carbon-metal bonds promise to be particularly good donors of hydrogen. The synthesis, structure, and redox reactions of one member of this group of compounds, tris[(triphenylstannyl)methyl]methane (2), are reported. Triphenylcarbenium is reduced to triphenylmethane less rapidly by stannane 2 than by bis[(triphenylstannyl)methyl]methane (11). The unexpectedly low reactivity of stannane 2 is due to the adoption of a C3 conformation in which the central carbon-hydrogen bond is sterically shielded and gauche to the adjacent carbon-tin bonds.