10271-32-6Relevant academic research and scientific papers
Direct Synthesis of Indanes via Iron-Catalyzed Dehydrative Coupling/Friedel–Crafts Cyclization of Two Different Alcohols
Sai, Masahiro
supporting information, p. 1102 - 1106 (2019/02/14)
We report herein a novel iron-catalyzed cascade dehydrative coupling/Friedel–Crafts cyclization of two different alcohols, providing a variety of indanes, which are ubiquitous substructures found in natural products, pharmaceuticals, and functional materi
Transfer off hydrogen from carbon-hydrogen bonds. Synthesis, structure, and reactions of tris[(triphenylstannyl)methyl]methane
Ducharme, Yves,Latour, Stephan,Wuest, James D.
, p. 208 - 211 (2008/10/08)
Compounds in which a carbon-hydrogen bond is adjacent to several carbon-metal bonds promise to be particularly good donors of hydrogen. The synthesis, structure, and redox reactions of one member of this group of compounds, tris[(triphenylstannyl)methyl]methane (2), are reported. Triphenylcarbenium is reduced to triphenylmethane less rapidly by stannane 2 than by bis[(triphenylstannyl)methyl]methane (11). The unexpectedly low reactivity of stannane 2 is due to the adoption of a C3 conformation in which the central carbon-hydrogen bond is sterically shielded and gauche to the adjacent carbon-tin bonds.
Scope and Limitations of Aliphatic Friedel-Crafts Alkylations. Lewis Acid Catalyzed Addition Reactions of Alkyl Chlorides to Carbon-Carbon Double Bonds
Mayr, Herbert,Striepe, Wilhelm
, p. 1159 - 1165 (2007/10/02)
Lewis acid catalyzed addition reactions of alkyl halides 1 with unsaturated hydrocarbons 2 have been studied. 1:1 addition products 3 are formed if the addends 1 dissociate faster than the corresponding products 3; otherwise, polymerization of 2 takes place.For reaction conditions under which 1 and 3 exist mainly undissociated, solvolysis constants of model compounds can be used to predict the outcome of any such addition reactions if systems with considerable steric hindrance are excluded.
