875559-85-6

Upstream product

• 50487-70-2 N-allylbenzenesulfonamide 
• 870-63-3 prenyl bromide 
• 98-09-9 benzenesulfonyl chloride 
• 106-95-6 allyl bromide 
• 99606-67-4 N-(3-methylbut-2-en-1-yl)benzenesulfonamide 
• 98-10-2 benzenesulfonamide 

Downstream Products

• 875559-87-8 benzoic acid 2-[1-benzenesulfonyl-4-(cyano-dimethyl-methyl)-pyrrolidin-3-yl]-1-ethoxythiocarbonylsulfanyl-ethyl ester 
• 50487-70-2 N-allylbenzenesulfonamide 

Relevant academic research and scientific papers

Silver(I)-Catalyzed Deprenylation of Allylsulfonamide Derivatives

The silver(I)-catalyzed deprenylation of sulfonamide bearing prenyl functional groups on the nitrogen atom has been developed. In this reaction, the prenyl moiety was selectively eliminated without allyl or benzyl cleavage on the nitrogen atom. In addition, geranyl was also applicable for this elimination reaction. Furthermore, sulfonamide possessing two prenyl groups underwent a double deprenylation to form the corresponding deprenylated sulfonamide. Thus, a novel reactivity between the silver cation and double bond was observed.

Cyano(ethoxycarbonothioylthio)methyl benzoate: A novel one-carbon radical equivalent

(Chemical Equation Presented) Cyano(ethoxycarbonothioylthio)methyl benzoate 3 has been prepared and shown to be an excellent one-carbon radical equivalent that can be applied for the introduction of an acyl unit via xanthate transfer radical addition to o