87564-75-8Relevant academic research and scientific papers
ELECTROCHEMICAL STUDIES ON ORGANOMETALLIC COMPOUNDS. V. ELECTROCHEMICAL OXIDATION OF THE ANIONS - AND -
Mugnier, Y.,Reeb, P.,Moise, C.,Laviron, E.
, p. 111 - 118 (1983)
In tetrahydrofuran with tetrabutylammonium hexafluorophosphate as supporting electrolyte, 1e electrochemical oxidation of - gives Co2(CO)8; in the presence of dimethylphenylphosphine (DMPP), the process consumes two electrons and + is obtained.The same cation is also obtained by 2 F axidation of - in the presence of DMPP.In all cases a radical intermediate is formed.
