ELECTROCHEMICAL STUDIES ON ORGANOMETALLIC COMPOUNDS. V. ELECTROCHEMICAL OXIDATION OF THE ANIONS - AND -

DOI: 10.1016/0022-328X(83)85123-7

Source and publish data:

Journal of Organometallic Chemistry p. 111 - 118 (1983)

Update date:2022-07-29

Topics:

Authors:

Mugnier, Y.

Reeb, P.

Moise, C.

Laviron, E.

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Article abstract of DOI:10.1016/0022-328X(83)85123-7

In tetrahydrofuran with tetrabutylammonium hexafluorophosphate as supporting electrolyte, 1e electrochemical oxidation of ^- gives Co2(CO)8; in the presence of dimethylphenylphosphine (DMPP), the process consumes two electrons and ⁺ is obtained.The same cation is also obtained by 2 F axidation of ^- in the presence of DMPP.In all cases a radical intermediate is formed.

Full text of DOI:10.1016/0022-328X(83)85123-7

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