87574-19-4Relevant academic research and scientific papers
Novel pyrrolo[1,2-a][3.1.6]benzothiadiazocine ring synthesis. Unusual Truce-Smiles type rearrangement of 1-{[1-(2-nitrophenyl)-1H-pyrrol-2-yl] sulfonyl(or sulfinyl)}acetone
Kimbaris, Athanasios,Cobb, Jonathan,Tsakonas, Georgios,Varvounis, George
, p. 8807 - 8815 (2004)
Reaction of 1-{[1-(2-nitrophenyl)-1H-pyrrol-2-yl]sulfonyl}acetone with sodium hydroxide with or without zinc gave 1-(2-nitrophenyl)(1H-pyrrol-2- ylsulfonyl)methane by a Truce-Smiles type of transformation and 1-(2-nitrophenyl)-2-methylsulfonylpyrrole by d
Novel Rearrangements of N-Arylpyrrolyl Sulphides (1)
Cheeseman, G. W. H.,Hawi, A. A.
, p. 591 - 594 (2007/10/02)
Base treatment of the pyrrolylthioacetate 2 and the pyrrolylthiocetonitrile 4 unexpectedly yielded a pyrrolothiazole 6 and 2-(α-cyano-2-nitrobenzyl)thiopyrrole (7), respectively.
