87587-56-2Relevant academic research and scientific papers
An efficient synthesis of a class of heterobifunctional photo-reactive crosslinkers, labels, and probes
Gano, Kyle W.,Monbouquette, Harold G.,Myles, David C.
, p. 2249 - 2251 (2007/10/03)
Aryl esters are selectively reduced with DIBAL-H in the presence of an azide functional group to provide access to 4-azido-2-alkoxybenzaldehydes in five steps with overall yields ranging from 72 to 78%. This methodology improves traditional approaches to this class of compounds, which suffer from poor overall yields (4-11%). Our approach can be used to synthesize a variety of new aryl azide cross-linkers, labels, and probes.
Approaches to Azepines: A New Azepine by the Photolysis of Dimethyl p-Azidosalicylate
Mustill, Reginald A.,Rees, Alun H.
, p. 5041 - 5043 (2007/10/02)
We have generated 3-methoxy-4-carbomethoxyphenylnitrene and 3,4-dimethoxyphenylnitrene under various conditions, in a search for new azepines.Unexpectedly, only the former, by photolysis of dimethyl p-azidosalicylate, gave an azepine.Intramolecular coordi
