876034-57-0

Upstream product

• 873093-21-1 4,5-dihydrothiazol-2-yl 3,4,6-tri-O-benzyl-1-thio-β-D-glucopyranoside 
• 31106-82-8 2-(bromomethyl)pyridine hydrobromide 
• 669775-77-3 1,2-O-(1-ethylthioethylidene)-α-D-glucopyranose 
• 64656-17-3 3,4,6-tri-O-acetyl-1,2-O-[1-(ethylsulfanyl)ethylidene]-α-D-glucopyranose 
• 873093-20-0 4,5-dihydrothiazol-2-yl 2-O-acetyl-3,4,6-tri-O-benzyl-1-thio-β-D-glucopyranoside 
• 852448-25-0 3,4,6-tri-O-benzyl-1,2-O-[1-(ethylsulfanyl)ethylidene]-α-D-glucopyranose 

Downstream Products

• 1083195-88-3 ethyl 2,3,4-tri-O-acetyl-6-O-(3,4,6-tri-O-benzyl-2-O-picolyl-β-D-glucopyranosyl)-1-thio-β-D-glucopyranoside 
• 873093-23-3 methyl 2,3,4-tri-O-benzyl-6-O-(3,4,6-tri-O-benzyl-2-O-picolinyl-β-D-glucopyranosyl)-α-D-glucopyranoside 

Relevant academic research and scientific papers

How the arming participating moieties can broaden the scope of chemoselective oligosaccharide synthesis by allowing the inverse armed-disarmed approach

(Chemical Equation Presented) A new method for stereocontrolled glycosylation and chemoselective oligosaccharide synthesis has been developed. It has been determined that complete 1,2-trans selectivity can be achieved with the use of a 2-O-picolyl moiety,

Development of an arming participating group for stereoselective glycosylation and chemoselective oligosaccharide synthesis

(Chemical Equation Presented) Armed and dangerous: A new armed-disarmed glycosylation strategy (see picture) allows chemoselective introduction of a 1,2-trans glycosidic linkage prior to other linkages through the use of a 2-O-picolyl moiety. This neighbo