31106-82-8

Basic information

• Product Name: 2-(Bromomethyl)pyridine hydrobromide
• Synonyms: 2-(BROMOMETHYL)PYRIDINE HYDROBROMIDE;2-(BROMOMETHYL)PYRIDINE HYDROBROMIDE, 98;2-(Bromomethyl)pyridine hydrobromide ,97.5%;2-BroMoMethylpyridine HBr;2-(BroMoMethyl)pyridine hydrobroMide, 98% 5GR;2-(BroMoMethyl)pyridine 2-(BroMoMethyl)pyridine hydrobroMide 98%
• CAS NO: 31106-82-8
• Molecular Formula: BrH*C₆H₆BrN
• Molecular Weight: 252.93
• Product Categories: Heterocycles;Heterocyclic Compounds;C6Heterocyclic Building Blocks;Halogenated Heterocycles;Heterocyclic Building Blocks;Pyridines
• Mol File: 31106-82-8.mol
• Article Data: 1

Chemical Properties

• Melting Point: 149-152 °C(lit.)
• Boiling Point: 201.7°Cat760mmHg
• Flash Point: 75.8°C
• Appearance: Off-white to pink to light brown/Crystalline Powder or Crystals
• Density: 1.533g/cm³
• Vapor Pressure: 0.433mmHg at 25°C
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• Solubility: soluble in Methanol
• CAS DataBase Reference: 2-(Bromomethyl)pyridine hydrobromide(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(Bromomethyl)pyridine hydrobromide(31106-82-8)
• EPA Substance Registry System: 2-(Bromomethyl)pyridine hydrobromide(31106-82-8)

Safety Data

• Hazard Codes: C
• Statements: 34-20/21/22
• Safety Statements: 22-26-36/37/39-45
• RIDADR: UN 3261 8/PG 2
• WGK Germany: 3
• HazardClass: 8
• PackingGroup: Ⅱ
• Hazardous Substances Data: 31106-82-8(Hazardous Substances Data)

Usage

Chemical Properties

off-white to pink crystalline powder

Uses

2-(Bromomethyl)pyridine hydrobromide may be used in the preparation of :2-[1-(pyridin-2-ylmethyl)-1H-1,2,3-triazol-4-yl]pyridine2-morpholin-4-yl-7-(pyridin-2-ylmethoxy)-4H-1,3-benzoxazin-4-one8-methyl-2-morpholin-4-yl-7-(pyridin-2-ylmethoxy)-4H-1,3-benzoxazin-4-onetrans-4-(4-(bis(pyridin-2-ylmethyl)amino)styryl)benzonitrile2-[N-(2-aminoethanethiol) methyl]-pyridine2-[N-(ethylenediamino)-methyl]-pyridine3-(carboxymethyl)-1-[(pyridin-2-yl)methyl]-3H-imidazol-1-ium trifluoroacetate3-[(S)-1-carboxy-2-methylpropyl]-1-[(pyridin-2-yl)methyl]-3H-imidazol-1-ium trifluoroacetate

General Description

2-(Bromomethyl)pyridine hydrobromide is a pyridine derivative. It participates in the synthesis of 7-nitrobenz-2-oxa-1,3-diazole (NBD) based colorimetric and fluorescence chemosensor.

InChI:InChI=1/C6H6BrN.BrH/c7-5-6-3-1-2-4-8-6;/h1-4H,5H2;1H

Upstream product

• 100-55-0 3-hydroxymethylpyridin 
• 10035-10-6 hydrogen bromide 

Downstream Products

• 170364-57-5 enzastaurin 
• 1192206-01-1 2-{[4-phenyl-1H-1,2,3-triazol-1-yl]methyl}pyridine 
• 1292767-69-1 methyl 3,5-bis(pyridin-2-ylmethoxy)benzoate 
• 1449300-89-3 5-(4-fluorophenyl)-4-oxo-1-(pyridin-2-ylmethyl)-1,4-dihydropyridine-3-carboxylic acid 
• 1449299-76-6 N-{4-[2-amino-5-(3,4-dimethoxyphenyl)pyridin-3-yl]phenyl}-5-(4-fluorophenyl)-4-oxo-1-(pyridin-2-ylmethyl)-1,4-dihydropyridine-3-carboxamide 
• 1222138-13-7 3-(benzyloxy)-5-[(1S,2S)-2-[(2-pyridylmethoxy)methyl]cyclopropyl]pyridine 
• 1029692-15-6 LY2452473 
• 1094610-78-2 C₁₉H₁₃BrF₆N₂S 
• 1094610-80-6 t-butyl N-(4-bromo-3,5-bis(trifluoromethyl)phenyl)-N-(2-pyridinylmethyl)aminoacetate 
• 1094610-47-5 C₂₀H₁₄ClF₆N₃ 
• 1200396-61-7 2-thiazolinyl 2,3,4-tri-O-benzyl-6-O-picolyl-1-thio-β-D-glucopyranoside 
• 1200396-62-8 ethyl 2,3,4-tri-O-benzyl-6-O-picolinyl-1-thio-β-D-glucopyranoside 
• 1200396-66-2 4-(pyridin-2-yl)thiazol-2-yl 2,3,4-tri-O-benzyl-6-O-picolyl-1-thio-β-D-glucopyranoside 
• 1018446-33-7 N-[1-(pyridin-2-ylmethyl)-1H-pyrazol-4-yl]-4-{[3-(trifluoromethyl)phenoxy]methyl}pyridine-2-carboxamide 

Relevant articles and documents

Optically pure heterobimetallic helicates from self-assembly and click strategies

Single diastereomer, diamagnetic, octahedral Fe(ii) tris chelate complexes are synthesised that contain three pendant pyridine proligands pre-organised for coordination to a second metal. They bind Cu(i) and Ag(i) with coordination geometry depending on the identity of the metal and the detail of the ligand structure, but for example homohelical (ΔFe, ΔCu) configured systems with unusual trigonal planar Cu cations are formed exclusively in solution as shown by VT-NMR and supported by DFT calculations. Similar heterobimetallic tris(triazole) complexes are synthesised via clean CuAAC reactions at a tris(alkynyl) complex, although here the configurations of the two metals differ (ΔFe, ΛCu), leading to the first optically pure heterohelicates. A second series of Fe complexes perform less well in either strategy as a result of lack of preorganisation.