876144-57-9

Upstream product

• 876144-62-6 (2R,3R)-3-(4-Methoxy-benzyloxy)-2-methyl-hex-5-enal 

Downstream Products

• 876144-60-4 (2R,6R)-2-[(2S,4S,6R,7S)-2,4-Bis-(tert-butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-7-methyl-non-8-ynyl]-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-tetrahydro-pyran 
• 876144-68-2 (2S,8S,9R,11S,13S)-11,13-Bis-(tert-butyl-dimethyl-silanyloxy)-14-{(2R,6R)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-tetrahydro-pyran-2-yl}-2-methoxy-1,9-bis-(4-methoxy-benzyloxy)-8-methyl-tetradec-6-yn-5-ol 
• 876144-71-7 (Z)-(2S,8S,9R,11S,13S)-11,13-Bis-(tert-butyl-dimethyl-silanyloxy)-14-{(2R,6R)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-tetrahydro-pyran-2-yl}-2-methoxy-1,9-bis-(4-methoxy-benzyloxy)-8-methyl-tetradec-6-en-5-ol 
• 876144-59-1 (Z)-(2S,8S,9R,11S,13S)-11,13-Bis-(tert-butyl-dimethyl-silanyloxy)-14-{(2R,6R)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-tetrahydro-pyran-2-yl}-2-methoxy-1,9-bis-(4-methoxy-benzyloxy)-8-methyl-tetradec-6-en-5-one 

Relevant academic research and scientific papers

Synthesis of the C1-C21 southern hemisphere of the originally proposed structure of spirastrellolide A

A stereocontrolled synthesis of the C1-C21 [6,6]-spiro-acetal-containing domain of the originally assigned structure of spirastrellolide A is reported, exploiting asymmetric boron aldol methodology and an alkyne addition to a C1