876144-68-2

Upstream product

• 876144-62-6 (2R,3R)-3-(4-Methoxy-benzyloxy)-2-methyl-hex-5-enal 
• 876144-70-6 1-Methoxy-4-((S)-2-methoxy-hex-5-enyloxymethyl)-benzene 
• 876144-57-9 (4R,5S)-7,7-Dibromo-4-(4-methoxy-benzyloxy)-5-methyl-hept-6-en-2-one 
• 876144-64-8 {6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-5,6-dihydro-2H-pyran-2-yl}-acetaldehyde 
• 876144-63-7 acetic acid 2-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-3,4-dihydro-2H-pyran-4-yl ester 
• 876144-58-0 {(2R,6R)-6-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-tetrahydro-pyran-2-yl}-acetaldehyde 
• 80910-01-6 (S)-2-[(4-methoxybenzyloxy)methyl]oxirane 
• 876144-69-3 (S)-1-(4-Methoxy-benzyloxy)-hex-5-en-2-ol 
• 250355-82-9 (-)-(2S)-2-[2-(tert-butyldiphenylsiloxy)ethyl]-2H-pyran-4(3H)-one 

Downstream Products

• 876144-59-1 (Z)-(2S,8S,9R,11S,13S)-11,13-Bis-(tert-butyl-dimethyl-silanyloxy)-14-{(2R,6R)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-tetrahydro-pyran-2-yl}-2-methoxy-1,9-bis-(4-methoxy-benzyloxy)-8-methyl-tetradec-6-en-5-one 
• 876144-71-7 (Z)-(2S,8S,9R,11S,13S)-11,13-Bis-(tert-butyl-dimethyl-silanyloxy)-14-{(2R,6R)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-tetrahydro-pyran-2-yl}-2-methoxy-1,9-bis-(4-methoxy-benzyloxy)-8-methyl-tetradec-6-en-5-ol 

Relevant academic research and scientific papers

Synthesis of the C1-C21 southern hemisphere of the originally proposed structure of spirastrellolide A

A stereocontrolled synthesis of the C1-C21 [6,6]-spiro-acetal-containing domain of the originally assigned structure of spirastrellolide A is reported, exploiting asymmetric boron aldol methodology and an alkyne addition to a C1