876152-36-2

Upstream product

• 7712-68-7 (1S,5R)-trans-pulegenic acid 
• 89-82-7 pulegone 
• 7712-70-1 ((1S)-2-isopropylidene-5t-methyl-cyclopent-r-yl)-methanol 
• 876152-54-4 tert-butyl(((1S,2R)-2-methyl-5-(propan-2-ylidene)cyclopentyl)methoxy)diphenylsilane 

Downstream Products

• 1268265-20-8 (4R,5R)-5-(((tert-butyldiphenylsilyl)oxy)methyl)-4-methylcyclopent-2-enone 
• 1268265-30-0 (4S,5R)-5-(((tert-butyldiphenylsilyl)oxy)methyl)-2-iodo-4-methylcyclopent-2-enone 
• 1268265-21-9 (4R,5R)-5-(((tert-butyldiphenylsilyl)oxy)methyl)-2,4-dimethylcyclopent-2-enone 
• 1268265-22-0 (1S,4R,5R)-5-(((tert-butyldiphenylsilyl)oxy)methyl)-2,4-dimethylcyclopent-2-enol 
• 1268265-19-5 (1S,4R,5R)-5-(((tert-butyldiphenylsilyl)oxy)methyl)-2,4-dimethylcyclopent-2-en-1-yl methyl carbonate 
• 1268265-23-1 ethyl 2-((1S,4S,5R)-4-(((tert-butyldiphenylsilyl)oxy)methyl)-2,5-dimethylcyclopent-2-en-1-yl)-3-oxo-3-((E)-styrylamino)propanoate 
• 1268265-17-3 3-((1R,4S,5R)-4-(((tert-butyldiphenylsilyl)oxy)methyl)-2,5-dimethylcyclopent-2-en-1-yl)-4-hydroxy-5-phenylpyridin-2(1H)-one 
• 1268265-24-2 (5aR,6R,7R,8R,8aS)-7-(((tert-butyldiphenylsilyl)oxy)methyl)-6-iodo-5a,8-dimethyl-4-phenyl-2,5a,6,7,8,8a-hexahydro-1H-cyclopenta[4,5]furo[3,2-c]pyridin-1-one 
• 1268265-26-4 (5aR,6R,7R,8R,8aS)-7-(hydroxymethyl)-6-iodo-5a,8-dimethyl-4-phenyl-2,5a,6,7,8,8a-hexahydro-1H-cyclopenta[4,5]furo[3,2-c]pyridin-1-one 
• 1268265-27-5 (5aS,8R,8aS)-5a,8-dimethyl-1-oxo-4-phenyl-2,5a,8,8a-tetrahydro-1H-cyclopenta[4,5]furo[3,2-c]pyridine-7-carbaldehyde 
• 1268265-28-6 (5aS,8R,8aS)-7-(1,3-dithiolan-2-yl)-5a,8-dimethyl-4-phenyl-2,5a,8,8a-tetrahydro-1H-cyclopenta[4,5]furo[3,2-c]pyridin-1-one 
• 864448-19-1 (5aS,8R,8aS)-5a,7,8-trimethyl-4-phenyl-2,5a,8,8a-tetrahydro-1H-cyclopenta[4,5]furo[3,2-c]pyridin-1-one 
• 1268265-29-7 (5aS,8R,8aS)-1-(methoxymethoxy)-5a,7,8-trimethyl-4-phenyl-8,8a-dihydro-5aH-cyclopenta[4,5]furo[3,2-c]pyridine 
• 876152-37-3 (5R,6R)-6-(tert-Butyl-diphenyl-silanyloxymethyl)-5-methyl-tetrahydro-pyran-2-one 

Relevant academic research and scientific papers

Total synthesis of citridone A

The first total synthesis of citridone A has been achieved through regioselective intramolecular iodocyclization and regio-and stereoselective Pd(0)-catalyzed coupling as key reactions.(Figure Presented)

Synthesis of the C14-C28 fragment of tetronasin

A synthesis of the C14-C28 fragment of Tetronasin features an S E2 reaction between a cationic η3-allylmolybdenum complex and and an α-metallated tetrahydrofuran. Georg Thieme Verlag Stuttgart.