87635-25-4Relevant academic research and scientific papers
NICKELA-HETERORINGE AUS NICKEL(0) UND PHENYLISOCYANAT
Hoberg, H.,Oster, B.W.,Krueger, C.,Tsay, Y.H.
, p. 365 - 373 (1983)
Phenylisocyanate reacts with (Lig)Ni0 systems in various ways depending on the ligand (Lig).Thus, with TMEDA as ligand, headtail linkage of the isocyanates occurs to give the nickela-5-ring (II), whereas triethylphosphine ligand causes the formation of a nickela-6-ring (V).The structure of II was determined chemically and that of V by X-ray analysis.The properties of these novel cyclic nickela compounds are described and the reaction courses are discussed.
