Journal of Organometallic Chemistry p. 365 - 373 (1983)
Update date:2022-08-04
Topics:
Hoberg, H.
Oster, B.W.
Krueger, C.
Tsay, Y.H.
Phenylisocyanate reacts with (Lig)Ni0 systems in various ways depending on the ligand (Lig).Thus, with TMEDA as ligand, headtail linkage of the isocyanates occurs to give the nickela-5-ring (II), whereas triethylphosphine ligand causes the formation of a nickela-6-ring (V).The structure of II was determined chemically and that of V by X-ray analysis.The properties of these novel cyclic nickela compounds are described and the reaction courses are discussed.
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