876499-26-2Relevant academic research and scientific papers
Ambient arylmagnesiation of alkynes catalysed by ligandless nickel(ii)
Xue, Fei,Zhao, Jin,Hor, T. S. Andy
, p. 10121 - 10123 (2013/10/22)
A simple and efficient catalytic arylmagnesiation of diarylacetylenes and aryl(alkyl)acetylenes is accomplished by NiCl2·6H2O at r.t. in the absence of stabilising ligands. The corresponding tetra-substituted alkenes can be obtained in good yields by subsequent treatment with different electrophiles. The Royal Society of Chemistry 2013.
