87666-86-2

Upstream product

• 87666-59-9 5'-Amino-m-terphenyl 
• 57830-60-1 3,5-diiodonitrobenzene 
• 5398-27-6 2,6-diiodo-4-nitroaniline 
• 100-01-6 4-nitro-aniline 
• 87666-58-8 5'-nitro-[1,1',3',1'']terphenyl 
• 92-06-8 1,3-diphenylbenzene 
• 34177-25-8 4-iodo-[1,1':3',1]terphenyl 

Downstream Products

• 92-52-4 biphenyl 
• 92-06-8 1,3-diphenylbenzene 
• 135-70-6 p-quaterphenyl 
• 3761-40-8 5'-phenyl-1,1':3',1'':4'',1'''-quaterphenyl 
• 21167-80-6 5',5''-diphenyl-m-quaterphenyl 
• 87871-73-6 2,6,5'-Triphenyl-m-terphenyl 
• 87666-64-6 3',6''-Diphenyl-o-quaterphenyl 
• 1410877-36-9 3-bromo-9-[1,1';3',1]terphenyl-5'-yl-9H-carbazole 

Relevant academic research and scientific papers

AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME

Disclosed is a long-life organic EL device having high luminous efficiency even after storage at high temperatures. Also disclosed is an aromatic amine derivative which enables to realize such an organic EL device. The aromatic amine derivative is represented by the following general formula (1). (In the formula (1), Ar1 is represented by the general formula (2) below, and Ar2 is represented by the general formula (3) below.)

AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME

Disclosed is a long-life organic EL device having high luminous efficiency even after storage at high temperatures. Also disclosed is an aromatic amine derivative which enables to realize such an organic EL device. The aromatic amine derivative is represented by the following general formula (1). (In the formula (1), Ar1 is represented by the general formula (2) below, and Ar2 is represented by the general formula (3) below.)

AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT ELEMENT EMPLOYING THE SAME

An aromatic amine derivative having a specific structure having m-terphenyl group and an organic electroluminescence device comprising a cathode, an anode and an organic thin film layer which is disposed between the cathode and the anode and comprises at least one layer comprising at least a light emitting layer, wherein at least one layer in the organic thin film layer comprises the aromatic amine derivative singly or as a component of a mixture. The organic electroluminescence device has a long life.

AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT DEVICE USING SAME

Provided are a novel aromatic amine derivative having an asymmetric structure and an organic electroluminescence device in which an organic thin film layer comprising a single layer or plural layers including at least a light emitting layer is interposed between a cathode and an anode, at least one layer in the above organic thin film layer contains the aromatic amine derivative described above in the form of a single component or a mixed component, whereby molecules are less liable to be crystallized; a yield in producing the organic electroluminescence device is enhanced; and a lifetime is extended.

AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT DEVICE USING SAME

Disclosed is an organic electroluminescent device wherein an organic thin film which is composed of one or more layers including at least a light-emitting layer is interposed between a cathode and an anode. Since at least one layer of the organic thin film contains a novel aromatic amine derivative, which has an asymmetric structure wherein two different amine units are bonded through a linking group, by itself or as a component of a mixture, molecules are hardly crystallized, thereby improving the production yield of the organic electroluminescent device. This organic electroluminescent device has a long life.

AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT DEVICE USING SAME

Disclosed is a novel aromatic amine derivative having an asymmetric structure. Also disclosed is an organic electroluminescent device wherein an organic thin film composed of one or more layers including at least a light-emitting layer is interposed between a cathode and an anode. Since at least one layer of the organic thin film contains the aromatic amine derivative by itself or as a component of a mixture, molecules are hardly crystallized, thereby improving the production yield of the organic electroluminescent device. This organic electroluminescent device has a long life.

Syntheses and Spectral Properties of several Branched-chain Polyphenyls containing 1,2,3-Trisubstituted Ring(s)

Nine polyphenyls, including six new compound, 3'-phenyl-o-quaterphenyl (3), 2,6-diphenyl-m- (4), 2,6-diphenyl-p-terphenyl (5), 2,6,5'-triphenyl-m-terphenyl (6), 2',2''-diphenyl-m-quaterphenyl (8), and 2'-(phenyl-d5)-m-terphenyl (9), were synthesized by the Ullmann coupling reaction of aryl iodide(s) or by the Karash-type coupling reaction of deuterated aryl Grignard reagent with aryl iodide catalyzed by bis(acetylacetonato)-nickel(II).Infrared studies of the polyphenyls showed that the range 730-770 cm-1, generally accepted as the position of the C-H out-of-plane bending bands of phenyl rings, should be widened slightly to 730-781 cm-1.The high frequency bands were found to be correlated closely to the sterically overcrowded structure of terminal rings.Proton magnetic resonance spectral studies indicated that the characteristic spectral features of the polyphenyls containing 1,2,3-trisubstituted ring(s) were fully consistent with their conformational aspects deduced from stereomodels.Ultraviolet spectral data suggeted that the most probable conformation of the highly crowded 3',6''-diphenyl-o-quaterphenyl (1) is one in which the interplanar angles of the pivot bonds between the 1,2,3-trisubstituted ring and three benzene rings are rather smaller than those of the less crowded 2'-phenyl-m-terphenyl (2).Keywords - Ullmann reaction; nickel-complex-catalyzed cross-coupling; quaterphenyl; deuterated quaterphenyl; quinquephenyl; sexiphenyl; polyphenyl; IR; UV; 1H-NMR