Cas 87686-27-9,dicarbonyl(η5-cyclopentadienyl)[N,N-bis(diphenylphosphino)glycine methyl ester-P,P']molybdenum(II) chloride

87686-27-9

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Basic information

Product Name: dicarbonyl(η5-cyclopentadienyl)[N,N-bis(diphenylphosphino)glycine methyl ester-P,P']molybdenum(II) chloride
Synonyms:
CAS NO:87686-27-9
Molecular Formula:
Molecular Weight: 709.957
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: dicarbonyl(η5-cyclopentadienyl)[N,N-bis(diphenylphosphino)glycine methyl ester-P,P']molybdenum(II) chloride(CAS DataBase Reference)
NIST Chemistry Reference: dicarbonyl(η5-cyclopentadienyl)[N,N-bis(diphenylphosphino)glycine methyl ester-P,P']molybdenum(II) chloride(87686-27-9)
EPA Substance Registry System: dicarbonyl(η5-cyclopentadienyl)[N,N-bis(diphenylphosphino)glycine methyl ester-P,P']molybdenum(II) chloride(87686-27-9)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 87686-27-9(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 87686-27-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,7,6,8 and 6 respectively; the second part has 2 digits, 2 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 87686-27:
(7*8)+(6*7)+(5*6)+(4*8)+(3*6)+(2*2)+(1*7)=189
189 % 10 = 9
So 87686-27-9 is a valid CAS Registry Number.

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87686-27-9Relevant academic research and scientific papers

CHIRALE CARBONYLCHLORO(η5-CYCLOPENTADIENYL)MOLYBDAEN- UND -WOLFRAM-KOMPLEXE MIT N,N-DIPHENYLPHOSPHINO-α-AMINOSAEUREESTERN: (η5-C5H5)(CO)(Cl)M(Ph2P)2NCHRCO2Me (M = Mo, W)

Fick, Hans-Georg,Beck, Wolfgang

, p. 83 - 94 (1983)

The reaction of (η5-C5H5)M(CO)3Cl (M=Mo, W) with optically active bis(diphenylphosphino)-α-(S)-aminoacid methylesters gives (η5-C5H5)(CO)(Cl)M(Ph2P)2NCHRCO2Me (II) with an "asymmetric" metal atom.The diastereomers of II can be easily

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