876954-49-3Relevant academic research and scientific papers
Formation of substituted tetrahydropyrans through oxetane ring opening: Application to the synthesis of C1-C17 fragment of salinomycin
Yadav,Singh, Vinay K.,Srihari
supporting information, p. 836 - 839 (2014/03/21)
The stereoselective synthesis of C1-C17 fragment of salinomycin is achieved. The strategy employs a desymmetrization approach and utilizes an intramolecular oxetane opening reaction with O-nucleophile to result in the tetrahydropyran skeleton as the key s
Stereocontrolled synthesis of C1-C17 fragment of narasin via a free radical-based approach
Guindon, Yvan,Brazeau, Jean-Francois,Guilbault, Audrey-Anne,Kochuparampil, Jummey,Mochirian, Philippe
supporting information; experimental part, p. 36 - 39 (2010/03/04)
Chemical Equation Presented An efficient synthesis of the C1-C17 western unit of narasin was achieved from (S)-Roche ester. Highlights in our synthesis include the successful exploitation of three stereoselective sequences of Lewis acid mediated reaction followed by free-radical-based hydrogen transfer.
Absolute stereochemistry of TT-1 (rasfonin), an α-pyrone-containing natural product from a fungus, Trichurus terrophilus
Akiyama, Kohki,Kawamoto, Souichi,Fujimoto, Haruhiro,Ishibashi, Masami
, p. 8427 - 8431 (2007/10/03)
The absolute stereochemistry of TT-1 (1=rasfonin), an α -pyrone-containing natural product from a Fungi Imperfecti, Trichurus terrophilus, was determined as 5R,6R,7S,9R, and 6′S on the basis of synthesis of diastereomers of two fragments of 1 in optically
