87698-81-5

Basic information

• Product Name: Pyrrolidine, 1-(2-broMophenyl)-
• Synonyms: Pyrrolidine, 1-(2-broMophenyl)-;1-(2-BroMophenyl)pyrrolidine
• CAS NO: 87698-81-5
• Molecular Formula: C₁₀H₁₂BrN
• Molecular Weight: 226.11298
• Mol File: 87698-81-5.mol
• Article Data: 15

Chemical Properties

• Appearance: /
• Storage Temp.: 2-8°C
• CAS DataBase Reference: Pyrrolidine, 1-(2-broMophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Pyrrolidine, 1-(2-broMophenyl)-(87698-81-5)
• EPA Substance Registry System: Pyrrolidine, 1-(2-broMophenyl)-(87698-81-5)

Safety Data

• Hazardous Substances Data: 87698-81-5(Hazardous Substances Data)

Usage

General Description

Pyrrolidine, 1-(2-bromophenyl)- is a chemical compound with the formula C10H12BrN. It is a heterocyclic organic compound containing a five-membered ring with a nitrogen atom. Pyrrolidine, 1-(2-bromophenyl)- is commonly used in organic synthesis as a reactant to create various other chemical compounds. It is also used as an intermediate in the production of pharmaceuticals and agrochemicals. Additionally, it can be used as a building block in the manufacturing of various chemicals and materials. Pyrrolidine, 1-(2-bromophenyl)- is a versatile chemical that has many applications in the chemical industry.

Upstream product

• 123-75-1 pyrrolidine 
• 583-55-1 1-Bromo-2-iodobenzene 
• 583-53-9 2,3-dibromobenzene 
• 110-52-1 1,4-dibromo-butane 
• 615-36-1 2-bromoaniline 
• 4096-21-3 N-phenylpyrrolidine 

Downstream Products

• 1147015-06-2 4-[(2-pyrrolidin-1-ylphenyl)ethynyl]-7H-pyrrolo[2,3-d]pyrimidine 
• 1352630-53-5 (3aR,5S)-ethyl 4-(4-methoxyphenyl)-1,2,3,3a,4,5-hexahydropyrrolo[1,2-a]quinazoline-5-carboxylate 
• 1352630-70-6 (3aS,5R)-ethyl 4-(4-methoxyphenyl)-1,2,3,3a,4,5-hexahydropyrrolo[1,2-a]quinazoline-5-carboxylate 
• 1352630-54-6 (3aR,5S)-ethyl4-phenyl-1,2,3,3a,4,5-hexahydropyrrolo[1,2-a]quinazoline-5-carboxylate 
• 1352630-55-7 (3aR,5S)-ethyl 4-p-tolyl-1,2,3,3a,4,5-hexahydropyrrolo[1,2-a]quinazoline-5-carboxylate 
• 1352630-56-8 (3aR,5S)-ethyl 4-(3,4-dimethoxyphenyl)-1,2,3,3a,4,5-hexahydropyrrolo[1,2-a]quinazoline-5-carboxylate 
• 1352630-57-9 (3aR,5S)-ethyl 4-(4-chlorophenyl)-1,2,3,3a,4,5-hexahydropyrrolo[1,2-a]quinazoline-5-carboxylate 

Relevant articles and documents

Dehydrogenation/(3+2) Cycloaddition of Saturated Aza-Heterocycles via Merging Organic Photoredox and Lewis Acid Catalysis

Herein, we report a photoinduced dehydrogenation/(3+2) cycloaddition reaction by merging organic photoredox and Lewis acid catalysis, providing a straightforward and efficient approach for directly installing a benzofuran skeleton on the saturated aza-heterocycles. In this protocol, we also describe a novel organic photocatalyst (t-Bu-DCQ) with the advantages of a wider redox potential, easy synthesis, and a low price. Furthermore, the stepwise activation mechanism of dual C(sp3)-H bonds was demonstrated by a series of experimental and computational studies.

Ruthenium-Catalyzed Carbonylative Coupling of Anilines with Organoboranes by the Cleavage of Neutral Aryl C-N Bond

Herein, we report the first ruthenium-catalyzed Suzuki-type carbonylative reaction of electronically neutral anilines via C(aryl)-N bond cleavage. Without any ligand and base, diaryl ketones can be obtained in moderate to high yields by using Ru3/su

A Structure–Activity Study of Nickel NNN Pincer Complexes for Alkyl-Alkyl Kumada and Suzuki–Miyaura Coupling Reactions

A new series of Ni NNN pincer complexes were synthesized and characterized. The main difference among these complexes is the substituents on the side arm amino group(s). No major structural difference was found except for the C–N–C angle of the various substituents and the ‘pseudo bite angle’ of the complexes. Four new complexes were efficient for the alkyl-alkyl Kumada reaction of primary alkyl halides, and among them, one complex was also efficient with secondary alkyl halides. The influence of the substituents on the catalytic performance of the Ni complexes in alkyl-alkyl Kumada and Suzuki–Miyaura cross-coupling reactions was systematically investigated. No correlation was found between the catalytic activity and the key structural parameters (C–N–C angle and ‘pseudo bite angle’), redox properties or Lewis acidity of the complexes.