877081-01-1

Basic information

• Product Name: Benzenesulfonamide, 4-methyl-N-[(1S,2R)-3-methyl-1-phenyl-2-[[2-(trimethylsilyl)ethoxy]methyl ]butyl]-
• CAS NO: 877081-01-1
• Molecular Formula: C24H37NO3SSi
• Molecular Weight: 447.714
• Mol File: 877081-01-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzenesulfonamide, 4-methyl-N-[(1S,2R)-3-methyl-1-phenyl-2-[[2-(trimethylsilyl)ethoxy]methyl ]butyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfonamide, 4-methyl-N-[(1S,2R)-3-methyl-1-phenyl-2-[[2-(trimethylsilyl)ethoxy]methyl ]butyl]-(877081-01-1)
• EPA Substance Registry System: Benzenesulfonamide, 4-methyl-N-[(1S,2R)-3-methyl-1-phenyl-2-[[2-(trimethylsilyl)ethoxy]methyl ]butyl]-(877081-01-1)

Safety Data

• Hazardous Substances Data: 877081-01-1(Hazardous Substances Data)

Upstream product

• 72203-95-3 ((S)-2-Methoxymethyl-pyrrolidin-1-yl)-[3-methyl-but-(E)-ylidene]-amine 
• 877080-96-1 (E,2R)-2-{[2-(trimethylsilyl)ethoxy]methyl}-N-[(S)-2-(methoxymethyl)pyrrolidin-1-yl]-3-methylbutan-1-imine 
• 98-59-9 p-toluenesulfonyl chloride 
• 76513-69-4 (2-trimethylethylsilylethoxy)methyl chloride 

Downstream Products

• 877081-06-6 (2S,3S)-3-isopropyl-2-phenyl-1-tosylazetidine 

Relevant articles and documents

Asymmetric synthesis of substituted azetidine type α- and β-amino acids

A versatile asymmetric synthesis of 3-substituted azetidine-2-carboxylic acids and 2-substituted azetidine-3-carboxylic acids via 1,3-amino alcohols with excellent stereoselectivities (de ≥ 96%, ee ≥ 96%) is reported. The high asymmetric inductions were achieved employing the SAMP/RAMP-hydrazone methodology. A phenyl moiety was used as a synthetic equivalent of the carboxylic acid function. In addition, the amino acids prepared were tested as organocatalysts in an asymmetric aldol reaction. Georg Thieme Verlag Stuttgart.