877374-65-7

Upstream product

• 877374-41-9 (2R)-2-[(1R,2R)-2-benzyloxy-1-benzyloxymethyl-2-methyl-hex-5-enyloxy]-4-triisopropylsilanyloxymethyl-pent-4-en-1-ol 
• 877374-45-3 (2R,3R,9R)-2-hydroxymethyl-3-methyl-9-(2-methyl-3-triethylsilanyloxy-propenyl)-7-triisopropylsilanyloxymethyl-2,3,4,5,8,9-hexahydrooxonin-3-ol 
• 877374-61-3 3-[(2R,8R,9R)-8-benzyloxy-9-benzyloxymethyl-8-methyl-4-triisopropylsilanyloxymethyl-2,3,6,7,8,9-hexahydro-oxonin-2-yl]-2-methylprop-2-en-1-ol 
• 877374-64-6 3-{(2R,3R,9R)-3-methyl-9-[2-methyl-3-oxo-propenyl]-3-triethylsilanyloxy-7-triisopropylsilanyloxymethyl-2,3,4,5,8,9-hexahydro-oxonin-2-yl}acrylic acid isopropyl ester 
• 877374-31-7 (4S)-3-{(2R)-2-[(1R,2R)-2-benzyloxy-1-benzyloxymethyl-2-methyl-hex-5-enyloxy]-4-triisopropylsilanyloxymethyl-pent-4-enoyl}-4-isopropyl-oxazolidin-2-one 
• 877374-44-2 (2R,3R,9R)-3-benzyloxy-2-benzyloxymethyl-3-methyl-9-(2-methyl-3-triethylsilanyloxy-propenyl)-7-triisopropylsilanyloxymethyl-2,3,4,5,8,9-hexahydrooxonine 
• 877374-47-5 3-{(2R,3R,9R)-3-methyl-9-[2-methyl-3-triethylsilanyloxy-propenyl]-3-triethylsilanyloxy-7-triisopropylsilanyloxymethyl-2,3,4,5,8,9-hexahydro-oxonin-2-yl}acrylic acid isopropyl ester 
• 758716-28-8 (4S)-3-{2-[(1R,2R)-2-benzyloxy-1-benzyloxymethyl-2-methyl-hex-5-enyloxy]-acetyl}-4-isopropyl-oxazolidin-2-one 
• 758716-27-7 (2R,3R)-1,3-bis-benzyloxy-2-(4-methoxy-benzyloxy)-3-methyl-hept-6-ene 
• 758716-23-3 (1R,2R)-(2-benzyloxy-1-benzyloxymethyl-2-methyl-hex-5-enyloxy)-acetic acid 
• 758716-26-6 (2R,3R)-1-benzyloxy-2-(4-methoxy-benzyloxy)-3-methyl-hept-6-en-3-ol 
• 13154-24-0 triisopropylsilyl chloride 
• 877374-63-5 3-{(2R,3R,9R)-9-[3-hydroxy-2-methyl-propenyl]-3-methyl-3-triethylsilanyloxy-7-triisopropylsilanyloxymethyl-2,3,4,5,8,9-hexahydro-oxonin-2-yl}acrylic acid isopropyl ester 
• 877374-43-1 3-[(2R,8R,9R)-8-benzyloxy-9-benzyloxymethyl-8-methyl-4-triisopropylsilanyloxymethyl-2,3,6,7,8,9-hexahydro-oxonin-2-yl]-2-methyl-acrylic acid ethyl ester 

Downstream Products

• 877374-50-0 acetic acid 1-{4-benzyloxy-6,14-dimethyl-14-triethylsilanyloxy-10-triisopropylsilanyloxymethyl-15-oxatricyclo[6.6.1.0^2,7]pentadeca-5,10-dien-3-yl}-1-methyl-ethyl ester 

Relevant academic research and scientific papers

An intramolecular Diels-Alder approach to the eunicellins: Enantioselective total syntheses of ophirin B and astrogorgin

The enantioselective syntheses of the eunicellins ophirin B and astrogorgin have been completed. Ring-closing metatheses provide efficient access to the oxonene rings, and highly diastereoselective intramolecular Diels-Alder reactions resulted in the form