758716-23-3

Upstream product

• 758716-27-7 (2R,3R)-1,3-bis-benzyloxy-2-(4-methoxy-benzyloxy)-3-methyl-hept-6-ene 
• 758716-26-6 (2R,3R)-1-benzyloxy-2-(4-methoxy-benzyloxy)-3-methyl-hept-6-en-3-ol 
• 758716-24-4 (3R)-4-benzyloxy-3-(4-methoxy-benzyloxy)-butan-2-one 
• 758716-25-5 (2S)-1-benzyloxy-2-(4-methoxy-benzyloxy)-but-3-ene 
• 109613-59-4 (S)-1-(benzyloxy)but-3-en-2-ol 
• 79-08-3 bromoacetic acid 
• 2930-05-4 (S)-benzyl glycidyl ether 

Downstream Products

• 877374-32-8 Acetic acid (R)-2-((4R,5R)-4-but-3-enyl-4-methyl-2-phenyl-[1,3]dioxan-5-yloxy)-4-methyl-pent-4-enyl ester 
• 877374-56-6 Acetic acid (R)-2-((1R,2R)-2-benzyloxy-1-benzyloxymethyl-2-methyl-hex-5-enyloxy)-4-methyl-pent-4-enyl ester 
• 877374-60-2 (2R,8R,9R)-8-benzyloxy-9-benzyloxymethyl-8-methyl-4-triisopropylsilanyloxymethyl-2,3,6,7,8,9-hexahydro-oxonine-2-carbaldehyde 
• 877374-42-0 (2R,8R,9R)-(8-benzyloxy-9-benzyloxymethyl-8-methyl-4-triisopropylsilanyloxymethyl-2,3,6,7,8,9-hexahydro-oxonin-2-yl)-methanol 
• 877374-41-9 (2R)-2-[(1R,2R)-2-benzyloxy-1-benzyloxymethyl-2-methyl-hex-5-enyloxy]-4-triisopropylsilanyloxymethyl-pent-4-en-1-ol 
• 877374-61-3 3-[(2R,8R,9R)-8-benzyloxy-9-benzyloxymethyl-8-methyl-4-triisopropylsilanyloxymethyl-2,3,6,7,8,9-hexahydro-oxonin-2-yl]-2-methylprop-2-en-1-ol 
• 877374-43-1 3-[(2R,8R,9R)-8-benzyloxy-9-benzyloxymethyl-8-methyl-4-triisopropylsilanyloxymethyl-2,3,6,7,8,9-hexahydro-oxonin-2-yl]-2-methyl-acrylic acid ethyl ester 
• 877374-31-7 (4S)-3-{(2R)-2-[(1R,2R)-2-benzyloxy-1-benzyloxymethyl-2-methyl-hex-5-enyloxy]-4-triisopropylsilanyloxymethyl-pent-4-enoyl}-4-isopropyl-oxazolidin-2-one 
• 877374-65-7 2-{4-benzyloxy-6,14-dimethyl-14-triethylsilanyloxy-10-triisopropylsilanyloxymethyl-15-oxatricyclo[6.6.1.0^2,7]pentadeca-5,10-dien-3-yl}propan-2-ol 
• 877374-44-2 (2R,3R,9R)-3-benzyloxy-2-benzyloxymethyl-3-methyl-9-(2-methyl-3-triethylsilanyloxy-propenyl)-7-triisopropylsilanyloxymethyl-2,3,4,5,8,9-hexahydrooxonine 
• 877374-49-7 4-benzyloxy-6,14-dimethyl-14-triethylsilanyloxy-10-triisopropylsilanyloxymethyl-15-oxatricyclo[6.6.1.0^2,7]pentadeca-5,10-diene-3-carboxylic acid isopropyl ester 
• 877374-50-0 acetic acid 1-{4-benzyloxy-6,14-dimethyl-14-triethylsilanyloxy-10-triisopropylsilanyloxymethyl-15-oxatricyclo[6.6.1.0^2,7]pentadeca-5,10-dien-3-yl}-1-methyl-ethyl ester 
• 758716-49-3 (2R,8R,9R)-8-benzyloxy-9-benzyloxymethyl-4,8-dimethyl-2,3,6,7,8,9-hexahydro-oxonine-2-carbaldehyde 
• 758716-31-3 (2R,8R,9R)-(8-benzyloxy-9-benzyloxymethyl-4,8-dimethyl-2,3,6,7,8,9-hexahydro-oxonin-2-yl)-methanol 

Relevant academic research and scientific papers

An intramolecular Diels-Alder approach to the eunicellins: Enantioselective total syntheses of ophirin B and astrogorgin

The enantioselective syntheses of the eunicellins ophirin B and astrogorgin have been completed. Ring-closing metatheses provide efficient access to the oxonene rings, and highly diastereoselective intramolecular Diels-Alder reactions resulted in the form

Ah intramolecular Diels-Alder approach to the eunicelins: Enantioselective total synthesis of ophirin B

The enantioselective synthesis of the eunicellin ophirin B has been completed. A ring-closing metathesis provides efficient access to the oxonene ring, and a highly diastereoselective intramolecular Diels-Alder reaction results in the formation of the hyd