87745-43-5Relevant academic research and scientific papers
New approach for size- and shape-controlled preparation of Pd nanoparticles with organic ligands. Synthesis and application in catalysis
Ananikov, Valentine P.,Orlov, Nikolay V.,Beletskaya, Irina P.,Khrustalev, Victor N.,Antipin, Mikhail Yu.,Timofeeva, Tatiana V.
, p. 7252 - 7253 (2007)
A novel approach was developed to prepare Pd nanoparticles with organic ligands in high yields. The structural unit of the Pd species was constructed involving Pd-S bonds. The synthesized Pd particles were highly selective catalysts of S-H bond addition to alkynes under microwave heating. An X-ray diffraction study of one of the products of the addition reaction revealed unusual supramolecular organization of cation/anion layers. Copyright
Pd-NHC Catalytic System for the Efficient Atom-Economic Synthesis of Vinyl Sulfides from Tertiary, Secondary, or Primary Thiols
Degtyareva, Evgeniya S.,Burykina, Julia V.,Fakhrutdinov, Artem N.,Gordeev, Evgeniy G.,Khrustalev, Victor N.,Ananikov, Valentine P.
, p. 7208 - 7213 (2015/12/11)
Vinyl sulfides represent an important class of compounds in organic chemistry and materials science. Atom-economic addition of thiols to the triple bond of alkynes provides an excellent opportunity for environmentally friendly processes. We have found tha
