877466-05-2Relevant academic research and scientific papers
Anti versus syn opening of epoxides derived from 9-(3-deoxy-β-D- glycero-pent-3-enofuranosyl)adenine with Me3Al: Factors controlling the stereoselectivity
Kubota, Yutaka,Haraguchi, Kazuhiro,Kunikata, Mayumi,Hayashi, Mari,Ohkawa, Masaomi,Tanaka, Hiromichi
, p. 1099 - 1103 (2007/10/03)
Upon epoxidation with dimethyldioxirane, the 2′,5′-bis-O-silyl derivatives of 9-(3-deoxy-β-D-glyceropent-3-enofuranosyl)adenine gave the respective "3′,4′-up" epoxides exclusively. Reaction between these epoxides and Me3Al was investigated in d
