87762-61-6Relevant academic research and scientific papers
NEW SYNTHESIS OF DIETHYL ALKYLPHOSPHONATES AND DIETHYL ALKENYLPHOSPHONATES
Chang, Kyeaongho,Ku, Bonchul,Oh, Dong Young
, p. 1891 - 1898 (2007/10/02)
Organometallic reagents readily added to diethyl 1-(trimethylsilyl)vinylphosphonate 1 by virtue of the polarizing silyl group.Quenching with acetic acid, methyl iodide, and carbonyl compounds gave synthetically useful diethyl alkylphosphonates 6 and diethyl alkenylphosphonates 8 respectively.
Synthesis and Reactions of Phosphoryl-Substituted Sulfines
Porskamp, Pascal A. T. W.,Lammerink, Ben H. M.,Zwanenburg, Binne
, p. 263 - 268 (2007/10/02)
The synthesis of a variety of phosphoryl-substituted sulfines 5 by the reaction of α-silyl carbanions with sulfur dioxide is described.For characterization purposes the prepared sulfines were converted into their cycloadducts 6 with 2,3-dimethyl-1,3-butad
