87797-13-5Relevant articles and documents
Visible-Light-Mediated [4+2] Cycloaddition of Styrenes: Synthesis of Tetralin Derivatives
Wang, Leifeng,Wu, Fengjin,Chen, Jiean,Nicewicz, David A.,Huang, Yong
supporting information, p. 6896 - 6900 (2017/06/08)
We report a formal [4+2] cycloaddition reaction of styrenes under visible-light catalysis. Two styrene molecules with different electronic or steric properties were found to react with each other in good yield and excellent chemo- and regioselectivity. This reaction provides direct access to polysubstituted tetralin scaffolds from readily available styrenes. Sophisticated tricyclic and tetracyclic tetralin analogues were prepared in high yield and up to 20/1 diasteroselectivity from cyclic substrates.
Ring selectivity in the Na/EtOH reduction of 1-aryl-7-methoxynaphthalenes
Carre?o, M. Carmen,González-López, Marcos,Latorre, Alfonso,Urbano, Antonio
, p. 1601 - 1605 (2007/10/03)
Na/EtOH reduction of 1-aryl-7-methoxynaphthalenes occurred preferentially at the A-ring when no substituents were present at the ortho-positions of the aryl group (up to 100% selectivity), to afford 1-aryl-7-methoxy-1,2,3,4- tetrahydronaphthalenes. Ortho-
An approach to the biomimetic synthesis of aryltetralin lignans
Pelter, Andrew,Ward, Robert S.,Rao, Ramohan R.
, p. 2933 - 2938 (2007/10/02)
The BF3 catalysed cyclisation of 3-arylpropyl substituted quinone-methide ketals affords a mild, biomimetic route to aryltetralins. 1H- and 13C-NMR spectra of the products are reported.