877995-24-9

Upstream product

• 128-08-5 N-Bromosuccinimide 
• 7789-67-5 stannic bromide 
• 115160-05-9 1-bromo-2,4,6-tris[bis(trimethylsilyl)methyl]benzene 
• 135139-65-0 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl-trichloro stannane 

Downstream Products

• 877995-21-6 2-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-3-tert-butyl-1,2-dihydro-2-stannanaphthalene 
• 877995-22-7 2-(2,4,6-tris(bis(trimethylsilyl)methyl)phenyl)-2-bromo-3-tert-butyl-1,2-dihydro-2-stannanaphthalene 
• 1068655-40-2 2-(2,4,6-tris(bis(trimethylsilyl)methyl)phenyl)-2-chloro-3-tert-butyl-1,2-dihydro-2-stannanaphthalene 
• 1254037-04-1 ((Me₃Si)2CH)3C₆H₂(H)SnC₅H₆ 
• 1254037-01-8 ((Me₃Si)2CH)3C₆H₂(Br)SnC₅H₆ 
• 877995-20-5 2-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-3-tert-butyl-2-stannanaphthalene 

Relevant academic research and scientific papers

Generation of stannabenzenes and their properties

Stannabenzenes 3, neutral stannaaromatic compounds having the simplest aromatic unit, were successfully generated by the reaction of the corresponding bromostannanes 5-Br with lithium diisopropylamide in hexane at -40 °C. The generation of 3 was indicated

Synthesis and properties of stable 2-metallanaphthalenes of heavier group 14 elements

The first stable neutral stannaaromatic compound, 2-stannanaphthalene 1a, was synthesized by taking advantage of an extremely bulky and efficient steric protection group, 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl (Tbt). The molecular structure and aromaticity of 1a were discussed on the basis of X-ray crystallographic analysis, NMR, UV-vis, and Raman spectroscopy, cyclic voltammetry, and theoretical calculations. 2-Germanaphthalene 2a, which has a framework similar to that of 1a, was synthesized for comparison, and systematic elucidation was made for the properties of 2-metallanaphthalene systems containing a heavier group 14 element (Si, Ge, or Sn).