877995-20-5

Upstream product

• 135139-65-0 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl-trichloro stannane 
• 877995-21-6 2-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-3-tert-butyl-1,2-dihydro-2-stannanaphthalene 
• 211508-96-2 3-tert-butyl-1H-isotellurochromene 
• 877995-24-9 (2,4,6-tris(bis(trimethylsilyl)methyl)phenyl)tribromostannane 
• 877995-22-7 2-(2,4,6-tris(bis(trimethylsilyl)methyl)phenyl)-2-bromo-3-tert-butyl-1,2-dihydro-2-stannanaphthalene 
• 1068655-40-2 2-(2,4,6-tris(bis(trimethylsilyl)methyl)phenyl)-2-chloro-3-tert-butyl-1,2-dihydro-2-stannanaphthalene 

Downstream Products

• 877995-23-8 [η6-[2-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-3-tert-butyl-2-stannanaphthalene]]Cr(CO)3 

Relevant academic research and scientific papers

Synthesis and properties of stable 2-metallanaphthalenes of heavier group 14 elements

The first stable neutral stannaaromatic compound, 2-stannanaphthalene 1a, was synthesized by taking advantage of an extremely bulky and efficient steric protection group, 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl (Tbt). The molecular structure and aromaticity of 1a were discussed on the basis of X-ray crystallographic analysis, NMR, UV-vis, and Raman spectroscopy, cyclic voltammetry, and theoretical calculations. 2-Germanaphthalene 2a, which has a framework similar to that of 1a, was synthesized for comparison, and systematic elucidation was made for the properties of 2-metallanaphthalene systems containing a heavier group 14 element (Si, Ge, or Sn).

A stable neutral stannaaromatic compound: Synthesis, structure and complexation of a kinetically stabilized 2-stannanaphthalene

A kinetically stabilized 2-stannanaphthalene, the first example of a stable, neutral aromatic compound containing a tin atom, has been synthesized and fully characterized. The results of spectroscopic and crystallographic structural analyses of the compou