878052-91-6Relevant academic research and scientific papers
Acid-catalyzed Nazarov reaction controlled by β-alkoxy groups
Shindo, Mitsuru,Yaji, Kentaro,Kita, Taisuke,Shishido, Kozo
, p. 1096 - 1100 (2008/03/11)
Acid-catalyzed Nazarov reaction of β-alkoxy divinyl ketones providing 5-oxycyclopent-2-enones has been developed. The effects of the β-alkoxy group on the catalyst efficiency and the regioselectivity are based on the stabilization of the intermediates and
Synthesis of tetrasubstituted and functionalized enol ethers by E-selective olefination of esters with ynolates
Shindo, Mitsuru,Kita, Taisuke,Kumagai, Toshihiro,Matsumoto, Kenji,Shishido, Kozo
, p. 1062 - 1063 (2007/10/03)
We have developed the E-selective olefination of ester carbonyls to afford tetrasubstituted, functionalized olefins and the C-S insertion of thiol esters to give β-keto thiol esters via ynolates. Copyright
