87813-43-2Relevant academic research and scientific papers
THE PHOSPHA-COPE REARRANGEMENT OF 3-ARYL-3λ-PHOSPHA-1,5-HEXADIENE DERIVATIVES
Kawashima, Takayuki,Miki, Yasuaki,Tomita, Tetsuji,Inamoto, Naoki
, p. 501 - 504 (2007/10/02)
The title compounds were refluxed in hexanol to give quantitatively the O-hexyl aryl-4-pentenylphosphinate derivatives via transient monomeric metaphosphinates, which seem to be formed by the phospha-Cope rearrangement.Kinetic studies show that the reacti
