878800-60-3

Upstream product

• 4648-54-8 trimethylsilylazide 
• 792908-47-5 4-O-mesyl-6-O-benzyl-D-gulal 
• 878800-58-9 (1S,2R,6S)-2-Benzyloxymethyl-3,7-dioxa-bicyclo[4.1.0]hept-4-ene 

Downstream Products

• 1057522-40-3 C₁₅H₁₇N₃O₄ 
• 1057522-36-7 C₁₅H₁₇N₃O₄ 

Relevant academic research and scientific papers

Synthesis of diastereoisomeric 6-deoxy-d-allal- and 6-deoxy-d-galactal-derived allyl epoxides and examination of the regio- and stereoselectivity in nucleophilic addition reactions. Comparison with the corresponding 6-O-functionalized allyl epoxides

The new 6-deoxy-d-allal- and 6-deoxy-d-galactal-derived allyl epoxides 8α and 8β have been stereoselectively prepared and their behaviour as glycosyl donors in addition reactions with nucleophiles examined and compared with that of the corresponding 6-OR

Stereoselective uncatalyzed synthesis of 2,3-unsaturated-4-N-substituted- β-O-glycosides by means of a new D-galactal-derived N-(mesyl)-aziridine

The reaction of the new D-galactal-derived allylic aziridine 1β with O-nucleophiles (alcohols and monosaccharides) affords, in a high to complete β-stereoselectivity, the corresponding 2,3-unsaturated-β-O-glycosides bearing a β-N-functionality at C(4).