87890-72-0

Basic information

• Product Name: {(triphos)Rh(P₃S₃)}*C₆H₆
• CAS NO: 87890-72-0
• Molecular Weight: 994.82
• Mol File: 87890-72-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: {(triphos)Rh(P₃S₃)}*C₆H₆(CAS DataBase Reference)
• NIST Chemistry Reference: {(triphos)Rh(P₃S₃)}*C₆H₆(87890-72-0)
• EPA Substance Registry System: {(triphos)Rh(P₃S₃)}*C₆H₆(87890-72-0)

Safety Data

• Hazardous Substances Data: 87890-72-0(Hazardous Substances Data)

Upstream product

• 12092-47-6 di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium 
• 1314-85-8 phosphorus sulfide 
• 22031-12-5 [2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine] 

Relevant articles and documents

Cleavage of P4S3 and P4Se3 Cage Molecules Controlled by Transition Metal-Ligand Systems. X-Ray Crystal Structure of Rh(P3S3)>*C6H6

The reaction of tetraphosphorus trisulphide and tetraphosphorus triselenide with 2 (cod = cycloocta-1,5-diene) in the presence of triphos yields the compounds *C6H6, X = S or Se, which have been shown by X-ray analysis to contain the (triphos)Rh moiety replacing a basal P atom in the cage molecule.

PHOSPHORUS AND ARSENIC CHALCOGENIDES AS REAGENTS TOWARD TRANSITION METAL-LIGAND SYSTEMS

The compounds obtained by reacting the P4S3, P4Se3 and As4S3 cage molecules with various transition metal-ligand moieties are reported.The transition metal-ligand systems are bound either to the intact molecules or to fragments (hexa- or tri-atomic) origi