Cleavage of P4S3 and P4Se3 Cage Molecules Controlled by Transition Metal-Ligand Systems. X-Ray Crystal Structure of Rh(P3S3)>*C6H6

DOI: 10.1039/C39830000903

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 903 - 904 (1983)

Update date:2022-07-31

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Authors:

Vaira, Massimo Di

Peruzzini, Maurizio

Stoppioni, Piero

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Article abstract of DOI:10.1039/C39830000903

The reaction of tetraphosphorus trisulphide and tetraphosphorus triselenide with 2 (cod = cycloocta-1,5-diene) in the presence of triphos yields the compounds <(triphos)Rh(P3X3)>*C6H6, X = S or Se, which have been shown by X-ray analysis to contain the (triphos)Rh moiety replacing a basal P atom in the cage molecule.

Full text of DOI:10.1039/C39830000903

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